• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    An optical fiber comprises a glass fiber and a coating resin layer overlying the glass fiber, the coating resin layer having a primary resin layer and a secondary resin layer, the primary resin layer comprising a resin composition cured composition obtained by curing a resin composition comprising an oligomer, a monomer, and a photopolymerization initiator, wherein the oligomer is a reaction product of a polyol compound, an isocyanate compound, and a hydroxyl group-containing (meth) acrylate compound; a proportion of a primary hydroxyl group included in the polyol compound is 3.5% or less; and a Young's modulus of the secondary resin layer at -40 ° C is 1780 MPa or higher.
    公开号:FR3058411A1
    申请号:FR1760414
    申请日:2017-11-07
    公开日:2018-05-11
    发明作者:Noriaki IWAGUCHI；Masuo Iida；Kentaro Okamoto；Takashi Fujii
    申请人:Sumitomo Electric Industries Ltd；
    IPC主号:
    专利说明:

    058 411
    60414 ® FRENCH REPUBLIC
    NATIONAL INSTITUTE OF INDUSTRIAL PROPERTY © Publication number:
    (to be used only for reproduction orders)
    ©) National registration number
    COURBEVOIE
    ©) Int Cl 8 : C 03 C 25/24 (2017.01), C 03 C 25/285, 25/326, 25/1065, G 02 B 6/02, 6/44
    A1 PATENT APPLICATION
    FR 3 058 411 - A1
    ©) Date of filing: 07.11.17.(30) Priority: 07.11.16 JP 2016217190. © Applicant (s): SUMITOMO ELECTRIC INDUSTRIES, LTD. - JP. ©) Date of public availability of the request: 11.05.18 Bulletin 18/19. ©) Inventor (s): IWAGUCHI NORIAKI, IIDA MASUO, OKAMOTO KENTARO and FUJII TAKASHI. (56) List of documents cited in the preliminary search report: The latter was not established on the date of publication of the request. (© References to other related national documents: ©) Holder (s): SUMITOMO ELECTRIC INDUSTRIES, LTD .. ©) Extension request (s): @) Agent (s): CABINET BEAU DE LOMENIE. (54) FIBER OPTICS. ©) An optical fiber comprises a glass fiber and a coating resin layer covering the glass fiber, the coating resin layer having a primary resin layer and a secondary resin layer, the primary resin layer comprising a composition cured resin obtained by curing a resin composition comprising an oligomer, a monomer, and a photopolymerization initiator, wherein the oligomer is a reaction product of a polyol compound, an isocyanate compound, and a (meth) acrylate compound containing a hydroxyl group; a proportion of a primary hydroxyl group of hydroxyl groups included in the polyol compound is 3.5% or less; and a Young's modulus of the secondary resin layer at -40 ° C is 1,780 MPa or higher.
    BACKGROUND Optical fibers generally have a coating resin layer to protect their glass fiber. WO2014 / 168201 describes for example a coated optical fiber having a primary coating layer and a secondary coating layer.
    SUMMARY As the diameter of an optical fiber cable becomes smaller and the cable has several optical fibers, there is a need to increase the low temperature properties of optical fibers. The low temperature properties here are the increase in transmission loss when lateral pressure is applied at low temperatures. It is believed that a small increase in this transmission loss provides excellent properties at low temperatures.
    An object of the present invention is to provide optical fibers having excellent properties at low temperatures.
    To achieve the above object, an aspect of the present invention provides an optical fiber comprising a glass fiber and a coating resin layer covering the glass fiber, the coating resin layer having a layer of primary resin and a secondary resin layer, the primary resin layer comprising a cured resin composition obtained by curing a resin composition comprising an oligomer, a monomer, and a photopolymerization initiator, wherein the oligomer is a product of reaction of a polyol compound, an isocyanate compound, and a hydroxyl group-containing (meth) acrylate compound; a proportion of a primary hydroxyl group of hydroxyl groups included in the polyol compound is 3.5% or less; and a module of
    Young's secondary resin layer at -40 ° C is 1,780 MPa or higher.
    According to a particular aspect of the present invention, the proportion of the primary hydroxyl group is 2.5% or less and the Young's modulus is 1,970 MPa or higher.
    According to another particular aspect of the present invention, an outer diameter of the optical fiber is 210 µm or less.
    According to a particular aspect still different from the present invention, the polyol compound is an aliphatic polyether polyol having a molecular weight of 5,000 or less.
    According to a particular aspect which is still different from the present invention, the secondary resin layer comprises a pigment or a dye.
    The present invention can provide optical fibers having excellent properties at low temperatures.
    BRIEF DESCIPTION OF THE DRAWINGS [0006] FIG. 1 is a schematic transverse view illustrating an example of an optical fiber according to an embodiment of the present invention.
    DETAILED DESCRIPTION [Description of embodiments of the present invention]
    The specifics of an embodiment of the present invention will first be listed and described. An optical fiber according to one aspect of the present invention comprises a glass fiber and a coating resin layer covering the glass fiber, the coating resin layer having a primary resin layer and a secondary resin layer, the coating layer. primary resin comprising a cured resin composition obtained by curing a resin composition comprising an oligomer, a monomer, and a polymerization initiator, wherein the oligomer is a reaction product of a polyol compound, a compound isocyanate, and a (meth) acrylate compound containing a hydroxyl group; a proportion of a primary hydroxyl group of hydroxyl groups included in the polyol compound is 3.5% or less; and a Young's modulus of the secondary resin layer at -40 ° C is 1,780 MPa or higher.
    The polyol compound here is a compound having two or more hydroxyl groups and examples of the hydroxyl groups include a primary hydroxyl group and a secondary hydroxyl group. The present inventors have found that when a polyol compound, in which the proportion of a primary hydroxyl group is low, is used as the polyol compound constituting an oligomer used for the formation of a primary resin layer and that the the Young's modulus of a layer of secondary resin at low temperature is adjusted to a high value, the increase in transmission loss at low temperature can be reduced and the properties at low temperature are excellent, thereby completing the present invention. The proportion of a primary hydroxyl group of terminal hydroxyl groups included in the polyol compound can be 2.5% or less and the Young's modulus of the secondary resin layer μ at -40 ° C can be 1,970 MPa or higher. This can further reduce the increase in transmission loss at low temperatures to further improve the low temperature properties.
    From the point of view of the manufacture of an optical cable which can have several optical fibers, the external diameter of each optical fiber can be 210 μm or less. The outer diameter of each optical fiber is generally about 250 µm and as each optical fiber becomes thinner, the loss in transmission is more likely to deteriorate. On the contrary, if a thin optical fiber (thin coating resin layer) is provided with the secondary resin layer according to the above embodiment, the increase in transmission loss at low temperature can be reduced.
    Regarding Young's modulus, the polyol compound can be an aliphatic polyether polyol having an average molecular weight of 5,000 or less.
    The secondary resin layer may contain a pigment or a dye. In this case, the secondary resin layer is a colored layer, and this makes the resulting optical fiber can be easily distinguished.
    [Details of embodiments of the present invention]
    Specific examples of the optical fiber according to an embodiment of the present invention will be described below with reference to the drawing. Note that the present invention is not limited to these examples and is defined by the claims, and it is intended that all modifications in the meanings and scope of the claims and their equivalents are included. In the following description, the same elements have the same reference signs in the description of the drawing and a redundant explanation is omitted.
    (Optical fiber)
    FIG. 1 is a schematic transverse view illustrating an example of an optical fiber according to an embodiment of the present invention. An optical fiber 1 is provided with a glass fiber 10, which is an optical transmission medium, and with a coating resin layer 20.
    The glass fiber 10 has a core 12 and a sheath 14 and consists of a glass element, such as glass of SiO 2 . The glass fiber 10 transmits light introduced into the optical fiber 1. The core 12 is supplied for example in a region containing the central axis of the glass fiber 10. The core 12 can be made of SiO glass 2 pure and may further contain for example GeO 2 or fluorine. The sheath 14 is provided in a region surrounding the core 12. The sheath 14 has a refractive index lower than the refractive index of the core 12. The sheath 14 can be made of pure SiO 2 glass or can be consisting of SiO 2 glass containing fluorine.
    The external diameter of the glass fiber 10 is usually around 125 μm. The outer diameter of the optical fiber 1 is preferably 260 µm or less and may be 210 µm or less. In addition, the lower limit of the outer diameter of the optical fiber 1 is about 190 µm.
    The coating resin layer 20 has a primary resin layer 22, which is a first layer in contact with the glass fiber, and a secondary resin layer 24, which is a second layer in contact with the first layer. . The total thickness of the coating resin layer 20 is preferably 32.5 to 67.5 µm and may be 32.5 to 42.5 µm.
    The low temperature properties of the optical fiber tend to be better when the primary resin layer becomes more flexible and the secondary resin layer becomes harder at -40 ° C. As used herein, the coating resin layer is generally formed from a resin composition containing a urethane oligomer, and it is known that the urethane oligomer is a reaction product of a polyol compound with an isocyanate compound. The polyol compound has hydroxyl groups. Since a primary hydroxyl group causes less steric hindrance than a secondary hydroxyl group, a higher proportion of the secondary hydroxyl group of the hydroxyl groups means that the urethane oligomer is larger and less likely to aggregate at low temperature. Therefore, it is predicted that the Young's modulus of the low temperature coating resin layer will decrease. In addition, since the oligomer content of a resin composition used for the formation of the primary resin layer is higher than that of a resin composition used for the formation of the secondary resin layer, the resin layer primary is more susceptible to steric hindrance derived from the secondary hydroxyl group than the secondary resin layer.
    Young's modulus of the primary resin layer 22 at -40 ° C is preferably from 1 to 40 MPa and even better from 1 to 20 MPa or less.
    The Young's modulus of the secondary resin layer 24 is higher than that of the primary resin layer 22. With regard to improving the properties at low temperature, the Young's modulus of the secondary resin layer 24 at -40 ° C is 1,780 MPa or higher, preferably 1,900 MPa or higher, and more preferably 1,970 MPa or higher. The upper limit of the Young's modulus of the secondary resin layer 24 at -40 ° C is not particularly limited and may be 2,500 MPa or less.
    The primary resin layer 22 can be formed by curing a UV curable resin composition comprising a specific oligomer, a monomer and a photopolymerization initiator.
    The above oligomer is a urethane oligomer containing a (meth) acryloyl group obtained by reaction of a polyol compound, an isocyanate compound, and a (meth) acrylate compound containing a hydroxyl group. Two or more oligomers can be mixed and used. The oligomer is preferably contained from 40 to 80% by mass in a resin composition used for the formation of the primary resin layer.
    With regard to the improvement of the properties at low temperature, the proportion of a primary hydroxyl group of hydroxyl groups included in the polyol compound is 3.5% or less, preferably 3.0% or lower, and even better 2.5% or lower. The lower limit of the proportion of a primary hydroxyl group included in the polyol compound is not particularly limited and may be 1.5% or higher. The proportion of a primary hydroxyl group included in the polyol compound can be calculated by NMR measurement of the oligomer.
    Examples of the polyol compound include aliphatic polyether polyols, such as polypropylene glycol and polyethylene glycol. With respect to Young's modulus, the polyol compound is preferably an aliphatic polyether polyol having an average molecular weight of 5,000 or less and more preferably a polypropylene glycol having an average molecular weight of 1,000 to 4,500. molecular of the polyol compound can be determined for example by mass spectrometry.
    Examples of the isocyanate compound include 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, isophorone diisocyanate and 4,4'-dicyclohexylmethane diisocyanate. Examples of the (meth) acrylate compound containing a hydroxyl group include 2-hydroxyethyl (meth) acrylate, 2-hydroxybutyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, (meth ) 2-hydroxypropyl acrylate, 1,6-hexanediol mono (meth) acrylate, pentaerythritol tri (meth) acrylate, and tripropylene glycol di (meth) acrylate.
    As used here, the (meth) acrylate indicates a corresponding acrylate or methacrylate. The same rule also applies to a (meth) acrylic acid.
    The monomer is incorporated into a molecular chain of the oligomer and functions as a reactive diluent. It is possible to use for the monomer a monofunctional monomer having a polymerizable group or a multifunctional monomer having two or more polymerizable groups. Two or more monomers can be mixed and used.
    Examples of the monofunctional monomer include: N-vinyl monomers having a cyclic structure, such as N-vinylpyrrolidone, N-vinylcaprolactam, and (meth) acryloylmorpholine; and (meth) acrylate compounds, such as isobornyl (meth) acrylate, tricyclodecanyl (meth) acrylate, benzyl (meth) acrylate, dicyclopentanyl (meth) acrylate, (meth) acrylate 2-hydroxyethyl, ethoxylated nonylphenyl (meth) acrylate, phenoxyethyl (meth) acrylate, polypropylene glycol mono (meth) acrylate, lauryl (meth) acrylate, isooctyl (meth) acrylate, and isodecyl (meth) acrylate. Preferred among these are N-vinyl monomers having a cyclic structure with respect to increasing the cure rate.
    Examples of the multifunctional monomer include polyethylene glycol di (meth) acrylate, tricyclodecanediyldimethylene di (meth) acrylate, 1,6-hexanediol (meth) acrylate, tripropylene glycol di (meth) acrylate, trimethylolpropane tri (meth) acrylate, a di (meth) acrylate of a diol of ethylene oxide or propylene oxide adduct of a bisphenol compound, and a (meth) acrylate of epoxy in which di (meth) acrylate is added to the glycidyl ether of a bisphenol compound.
    When the temperature of use of the optical fiber is low, the physical properties (for example elongation) of the coating resin layer should not change rapidly. For this purpose, the glass transition temperature (Tg) of the primary resin layer is preferably lower than the lower limit of the use temperature. As the transmission loss at -40 ° C tends to increase, the monomer is preferably a monomer characterized in that the Tg of a homopolymer formed by homopolymerization of the monomer is 5 ° C or lower, and even better a monomer characterized in that the Tg is 0 ° C or lower. Among the monomers mentioned above, the preferred examples include 2-hydroxyethyl (meth) acrylate, ethoxylated nonylphenyl (meth) acrylate, phenoxyethyl (meth) acrylate, lauryl acrylate, (meth) acrylate isooctyl, and isodecyl (meth) acrylate.
    Can be used as photopolymerization initiator, an appropriate selected from known photoradical polymerization initiators. Examples of the photopolymerization initiator include initiators based on acylphosphine oxide and initiators based on acetophenone. Two or more photopolymerization initiators can be mixed and used. The photopolymerization initiator is preferably contained in an amount of 0.1 to 5% by mass in a resin composition used for the formation of the resin layer.
    Examples of initiators based on acylphosphine oxide include 2,4,6-trimethylbenzoyldiphenylphosphine oxide (brand name: Lucirin TPO; manufactured by BASF Inc.), 2,4 oxide, 4trimethylpentylphosphine, and 2,4,4-trimethylbenzoyldiphenylphosphine oxide.
    Examples of acetophenone-based initiators include 1-hydroxycyclohexan-1-ylphenylketone (brand name: Irgacure 184; manufactured by BASF Inc.), 2-hydroxy-2-methyl-1-phenylpropan-1 -one (brand name: Darocur 1173; manufactured by BASF Inc.), 2,2-dimethoxy-1,2,2-diphenylethan-l-one (brand name: Irgacure 651; manufactured by BASF Inc.), la 2 -methyl-l- (4-methylthiophenyl) -2-morpholinopropan-l-one (brand name: Irgacure 907; manufactured by BASF Inc.), 2-benzyl-2-dimethylamino-l- (4-morpholinophenyl) - butanone-1 (brand name: Irgacure 369; manufactured by BASF Inc.), 1-hydroxycyclohexylphenylketone, 2,2-dimethoxy-2-phenylacetophenone, and l- (4-isopropylphenyl) -2-hydroxy-2- methylpropan-lone.
    As regards improving the hardening performance of the primary resin layer, an initiator based on phosphorus-containing acylphosphine oxide is preferably used as the photopolymerization initiator.
    The secondary resin layer 24 may for example be formed by curing a UV-curable resin composition containing an oligomer, a monomer, and a photopolymerization initiator (provided that this composition is different from a composition of resin used for the formation of the primary resin layer 22). As a photopolymerization initiator added to the secondary resin layer 24, a suitable compound chosen from the examples cited above used for the primary resin layer 22 can be used. The oligomer is preferably contained in an amount of 20 to 60 % by mass in a resin composition used for the formation of the secondary resin layer.
    Note that the secondary resin layer 24 constituting the coating resin layer 20 may be surrounded by a colored layer which is an ink layer in order to distinguish one optical fiber from the other. The secondary resin layer 24 may otherwise be a colored layer.
    As regards the improvement for distinguishing one optical fiber from the other, the colored layer preferably contains a pigment or a dye. An example of the pigment includes: color pigments, such as carbon black, titanium oxide, and zinc flower; and inorganic pigments, such as magnetic powders (for example, y-Fe2O3, a mixed crystal of y-Fe2O3 and Y-Fe 3 O 4 , CrO2, cobalt ferrite, iron oxide bonded to cobalt, ferrite of barium, Fe-Co, Fe-Co-Ni), MIO, zinc chromate, strontium chromate, aluminum tripolyphosphate, zinc, alumina, glass, and mica. It is also possible to use organic pigments, such as azo pigments, phthalocyanine pigments, and coloring lacquer pigments. The pigments can be subjected to treatments, such as various surface modifications and conversion to a composite pigment.
    EXAMPLES The present invention will be described in detail with reference to the examples, but the present invention is not limited to these examples. [Preparation of resin composition used for the formation of primary resin layer]
    Each resin composition used to form a primary resin layer was prepared by mixing 2,4,6-trimethylbenzoyldiphenylphosphine oxide (brand name: Lucirin TPO; manufactured by BASF Inc.), N- vinylcaprolactam, an ethoxylated nonylphenyl acrylate, and a urethane acrylate obtained by reaction of a polypropylene glycol with a diisocyanate and hydroxyethyl acrylate, so that the Young's modulus of the primary resin layer was 12 MPa at -40 ° C. In addition, polypropylene glycol was used, each polypropylene glycol having a proportion of primary hydroxyl group as shown in Table 1 or 2.
    [Preparation of resin composition used for the formation of a secondary resin layer]
    Each resin composition used for the formation of a secondary resin layer was prepared by mixing Irgacure 184, Lucirin TPO, 1,6-hexanediol diacrylate, an epoxy acrylate based on bisphenol, and an acrylate of urethane obtained by reaction of a polypropylene glycol with a diisocyanate and hydroxyethyl acrylate, so that the Young's modulus of the secondary resin layer was as shown in Table 1 or 2.
    [Manufacture of optical fibers]
    In Examples 1 to 5, 7, and 9 and in Comparative Examples 1 to 5, optical fibers were made having an external diameter of 245 µm by forming a layer of primary resin having a thickness of 35 µm on the circumference d a glass fiber having an external diameter of 125 µm made up of a core and a sheath, and then forming a layer of secondary resin having a thickness of 25 µm around the circumference of the layer of primary resin.
    In Examples 6, 8 and 10, optical fibers were produced having an external diameter of 200 μm by forming a layer of primary resin having a thickness of 17.5 μm on the circumference of a glass fiber having an outer diameter of 125 µm made up of a core and a sheath, and then forming a secondary resin layer having a thickness of 20 µm around the circumference of the primary resin layer.
    In Example 11, an optical fiber was made having an external diameter of 200 μm by forming a layer of primary resin having a thickness of 17.5 μm on the circumference of a glass fiber having an external diameter. of 125 µm consisting of a core and a sheath, and then forming a colored secondary resin layer having a thickness of 20 µm around the circumference of the primary resin layer. Note that Example 11 used a resin composition used for the formation of the secondary resin layer, where 5 parts by mass of an organic pigment were mixed in the resin composition. [Evaluation of optical fibers]
    The low temperature properties of the manufactured optical fibers were evaluated. The results are shown in Tables 1 to 2.
    (Young's modulus of the secondary resin layer)
    Each optical fiber was first immersed in a solvent (ethanol: acetone = 3: 7) and the coating resin layer was drawn from the glass fiber to prepare a sample (having a length of 50 mm or higher). The sample was then used for a tensile test (calibration length: 25 mm) at -40 ° C to determine the Young's modulus of the secondary resin layer from a 2.5% secant modulus.
    (Low temperature properties)
    Each optical fiber was wound around a glass spool to form a single layer of the optical fiber under a tension of 50 g; and the transmission characteristics of an optical signal having a wavelength of 1550 nm under temperature conditions of 23 ° C and -40 ° C were measured to calculate the transmission loss at 23 ° C and - 40 ° C, respectively.
    When the difference calculated by subtracting the transmission loss at 23 ° C from the transmission loss at -40 ° C was less than 0 dB / km, the properties at low temperature were noted by A; when the difference was 0 dB / km or more and less than 0.01 dB / km, the properties at low temperature were noted by B; and when the difference was 0.01 dB / km or higher, the low temperature properties were scored by C. A rating of B and higher was then acceptable.
    [Table 1]
    Example Primary resin layer Secondary resin layer Low temperature properties Proportion (%) of primary hydroxyl group Young's modulus (MPa) at -40 ° C 1 3.5 1,830 B 2 2.5 1,780 B 3 1.7 1,880 B 4 3.2 1,992 B 5 2.5 2,020 AT 6 1.5 2,010 AT 7 1.8 1,973 AT 8 2.2 2,040 AT 9 2.1 2,090 AT 10 2.0 1,980 AT 11 2.0 1,980 AT
    [Table 2]
    ExampleComparative Primary resin layer Secondary resin layer Low propertiestemperature Proportion (%) of primary hydroxyl group Young's modulus (MPa) at -40 ° C 1 5.0 1,811 VS 2 4.0 1,799 VS 3 6.0 1,760 VS 4 5.0 1,580 VS 5 3.5 1,680 VS
    It was found that the optical fibers manufactured in the examples exhibited excellent properties at low temperature because they exhibited a small increase in the loss of transmission at low temperature.
    权利要求:
    Claims (5)
    [1" id="c-fr-0001]
    1. An optical fiber comprising a glass fiber and a coating resin layer covering the glass fiber, the coating resin layer having a primary resin layer and a secondary resin layer, the primary resin layer comprising a composition of cured resin obtained by curing a resin composition comprising an oligomer, a monomer, and a photopolymerization initiator, characterized in that the oligomer is a reaction product of a polyol compound, an isocyanate compound , and a (meth) acrylate compound containing a hydroxyl group;
    a proportion of a primary hydroxyl group of hydroxyl groups included in the polyol compound is 3.5% or less; and a Young's modulus of the secondary resin layer at -40 ° C is 1,780 MPa or higher.
    [2" id="c-fr-0002]
    2. Optical fiber according to claim 1, characterized in that the proportion of the primary hydroxyl group is 2.5% or less and the Young's modulus is 1 970 MPa or higher.
    [3" id="c-fr-0003]
    3. Optical fiber according to claim 1 or 2, characterized in that an external diameter of the optical fiber is 210 µm or less.
    [4" id="c-fr-0004]
    4. Optical fiber according to any one of claims 1 to 3, characterized in that the polyol compound is an aliphatic polyether polyol having a molecular weight of 5,000 or less.
    [5" id="c-fr-0005]
    5. Optical fiber according to any one of claims 1 to 4, characterized in that the secondary resin layer comprises a pigment or a dye.
    1/1
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    法律状态:
    2018-10-24| PLFP| Fee payment|Year of fee payment: 2 |
    2019-09-30| PLFP| Fee payment|Year of fee payment: 3 |
    2020-06-26| PLSC| Publication of the preliminary search report|Effective date: 20200626 |
    2020-10-01| PLFP| Fee payment|Year of fee payment: 4 |
    2021-10-01| PLFP| Fee payment|Year of fee payment: 5 |
    优先权:
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    JP2016217190|2016-11-07|
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